A critical review on plasma-catalytic removal of VOCs: Catalyst development, process parameters and synergetic reaction mechanism

It is urgent to control the emission of volatile organic compounds (VOCs) due to their harmful effects on the environment and human health. A hybrid system integrating non-thermal-plasma and catalysis is regarded as one of the most promising technologies for VOCs removal due to their high VOCs removal efficiency, product selectivity and energy efficiency. This review systematically documents the main findings and improvements of VOCs removal using plasma-catalysis technology in recent 10 years. To better understand the fundamental relation between different aspects of this research field, this review mainly addresses the catalyst development, key influential factors, generation of by-products and reaction mechanism of VOCs decomposition in the plasma-catalysis process. Also, a comparison of the performance in various VOCs removal processes is provided. Particular emphasis is given to the importance of the selected catalyst and the synergy of plasma and catalyst in the VOCs removal in the hybrid system, which can be used as a reference point for future studies in this field. [Display omitted] •Recent process achieved in VOCs removal in plasma-catalysis system are summarized.•The main influential factors affecting the VOCs removal are discussed.•The synergetic interactions between plasma and catalyst are provided.•The properties of catalyst suitable for plasma-catalysis system are summarized.•The comparison of the performance of various VOCs removal process is presented.