Solid-state reactions in the Al-Fe system induced by ball milling of elemental powders

Elemental aluminium and iron powders have been mechanically alloyed in the atomic Al:Fe ratios of 1:1 and 1:3. The structural evolution of the samples was followed by x-ray diffraction and differential calorimetry. Extended milling caused the formation of an almost completely disordered bcc solid solution instread of the equilibrium B2 and DO sub 3 compounds. Upon heating to 700 deg C the formation of the B2 phase was observed in the equiatomic samples and no significant variation of the long-range state of order in the iron-rich samples. Upon heating of samples pre-milled for short or intermediate times, at approx400 deg C, the nucleation and growth of Al sub 5 Fe sub 2 was observed which, upon further heating to 700 deg C, transformed to the B2 phase or to the bcc solid solution, depending on the sample composition. These results suggest that the solid-state reactions proceed through diffusion of iron atoms in the Al layers, and that for an iron concentration in these layers < approx50 at.%, the Al(Fe) solid solution could be in a metastable phase.