Carbon nanotube-based materials for persulfate activation to degrade organic contaminants: Properties, mechanisms and modification insights

Removal of harmful organic matters from environment has great environmental significance. Carbon nanotube (CNT) materials and their composites have been demonstrated to possess excellent catalytic activity towards persulfate (PS) activation for the degradation of organic contaminants. Herein, detailed information concerning the function, modification methods and relevant mechanisms of CNT in persulfate-based advanced oxidation processes (PS-AOPs) for organic pollutant elimination has been reviewed. The activation mechanism of PS by CNT might include radical and nonradical pathways and their synergistic effects. The common strategies to improve the stability and catalytic capability of CNT-based materials have also been put forward. Furthermore, their practical application potential compared with other catalysts has been described. Finally, the challenges faced by CNT in practical application are clearly highlighted. This review should be of value in promoting the research of PS activation by CNT-based materials for degradation of organic pollutants and the corresponding practical applications. [Display omitted] •Application of CNT based composites presents great potential in PS activation.•OFGs, defects and high conductivity are conducive to activation.•Both radical and nonradical pathways are responsible for the activation.•Crossover technologies might be future research direction.