Co-composting of biochar and nitrogen-poor organic residues: Nitrogen losses and fate of polycyclic aromatic hydrocarbons

•Simultaneous immobilization and mineralization of biochar PAHs during composting.•Biochar favors a slower release of mineral N from mature compost.•Biochar increases water holding capacity and decreases bulk density of compost.•The high C:N ratio did not hinder the composting process. Composting re...

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Veröffentlicht in:Waste management (Elmsford) 2022-04, Vol.143, p.84-94
Hauptverfasser: Gustavo Adolfo, Gutiérrez-Fernández, Wolf-Anno, Bischoff, Martin, Ricker, Christina, Siebe
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Sprache:eng
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Zusammenfassung:•Simultaneous immobilization and mineralization of biochar PAHs during composting.•Biochar favors a slower release of mineral N from mature compost.•Biochar increases water holding capacity and decreases bulk density of compost.•The high C:N ratio did not hinder the composting process. Composting recycles nutrients and biodegrades organic pollutants, but often results in N leaching. Biochar can enhance the composting process and reduce N losses. Research, however, has focused on composting N-rich residues; also, information on the fate of biochar polycyclic aromatic hydrocarbons (PAHs) during composting is scarce. We explored the composting of biochar with N-poor organic residues as a strategy to reduce N losses and biochar PAHs. A small-scale composting experiment was performed with three treatments: 100% yard residues and two mixtures of 85% yard residues and 15% gasification- or pyrolysis-derived biochar. Temperatures were recorded daily during composting and Nlosses and changes in PAHs loads were calculated. Results across all treatments showed overall low N losses, likely caused by low temperatures and N contents, circumneutral pH values, and absence of leachate, and simultaneous immobilization and mineralization of PAH contents. Treatments with biochar showed a slower release of inorganic N (NO3--N and NH4+-N), although they also had overall lower inorganic N contents. This slower release of inorganic N may relate to biochar’s high surface area. We conclude that biochar provides valuable benefits for N-poor composting, and that composting should be further explored as a promising strategy to reduce the contents of PAHs in biochar.
ISSN:0956-053X
1879-2456
DOI:10.1016/j.wasman.2022.02.025