Dynamic [1]rotaxanes via a reversible covalent bond and host-guest anion recognition

Dynamic [1]rotaxanes via a reversible covalent bond and host-guest anion recognition

Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(I) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3815-3818
Hauptverfasser: Del Mauro, Arico, Kokan, Zoran, Šindelář, Vladimír
Format: Artikel
Sprache:eng
Schlagworte:
Acetonitrile
Anions
Covalent bonds
Recognition
Rotaxanes
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Zusammenfassung:Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(I) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00779g