Defect‐Rich, Highly Porous PtAg Nanoflowers with Superior Anti‐Poisoning Ability for Efficient Methanol Oxidation Reaction

The design of efficient and sustainable Pt‐based catalysts is the key to the development of direct methanol fuel cells. However, most Pt‐based catalysts still exhibit disadvantages including unsatisfied catalytic activity and serious CO poisoning in the methanol oxidation reaction (MOR). Herein, highly porous PtAg nanoflowers (NFs) with rich defects are synthesized by using liquid reduction combining chemical etching. It is demonstrated that the proportion of precursors determines the inhomogeneity of alloy elements, and the strong corrosiveness of nitric acid to silver leads to the eventual porous flower‐like structure. Impressively, the optimal etched Pt1Ag2 NFs have the mixed defects of surface steps, dislocations, and bulk holes, and their mass activity (1136 mA mgPt−1) is 2.6 times higher than that of commercial Pt/C catalysts, while the ratio of forward and backward peak current density (If/Ib) can reach 3.2, exhibiting an excellent anti‐poisoning ability. Density functional theory calculations further verify their high anti‐poison properties from both an adsorption and an oxidation perspective of CO intermediate. The introduction of Ag makes it easier for CO to be oxidized and removed. This study provides a facile approach to prepare rich defects and porous alloy with excellent MOR performance and superior anti‐poisoning ability. Highly porous E‐PtAg nanoflowers (NFs)/C with rich defects are synthesized by combing liquid reduction and chemical etching. The optimal E‐Pt1Ag2 NFs/C with the mixed defects of surface steps, dislocations, and bulk holes exhibit excellent catalytic activity and superior anti‐CO poisoning ability for the methanol oxidation reaction, demonstrating an effective strategy to enhance the properties of the alloy electrocatalysts.