Surface morphology and compound layer pores of plasma nitrocarburized low carbon steel

This article deals with various aspects of nitrocarburizing of AISI 1010 steel by DC plasma at 600 deg C. The initial stages of nitride formation and the effects of surface bombardment by hydrogen plasma species, and the effect of treatment current density on the surface morphology, were investigated in detail. The results show that in the pearlitic region carbides are removed during treatment in hydrogen plasma and that the current density influences the surface morphology significantly. A porous surface formed in a 1 min treatment under high current density (8 mA/cm exp 2 ), whereas a lower current density (2.4 mA/cm exp 2 ) resulted in a highly stressed surface attributed to uneven thermal gradients. Iron nitrides were identified on the surface in either set of conditions. A pure epsilon compound layer was obtained by plasma nitrocarburizing for 6 h and quenching. The pores in this layer are discussed in view of the 1 min treatment results and are also compared to those observed in a nitriding treatment. The lack of carbon species in the nitriding plasma results in different mechanisms for pore formation and growth during the treatment. These results are discussed in view of current models for plasma nitriding and gas nitrocarburizing.