Can the Thermophoretic Mobility of Uncharged Colloids Be Predicted?

The thermophoretic motion of nonionic colloids in an inhomogeneous temperature field is due to the solvent–colloid dispersion interactions. The latter form an attractive near-particle “gravity” field that leads to sinking of the colder solvent layers toward a colloid. The spatial extension of this microconvective motion is comparable to the size of the colloids, which prove to be small enough to observe their own regular thermophoretic drift to the cold. The Boussinesq equations of convection are augmented by the boundary conditions at the characteristic molecular distance dividing the immovable and motile solvent layers. For organic liquids, this distance proves to be a property of pure solvent. The thermophoretic mobilities are found for colloids with and without surfacted layers. They are determined by the bulk properties of substances and the Hamaker constant of the solvent–solute interactions. The mobilities weakly (logarithmically) depend on the size of colloids and tend to a universal value in the limiting case of strongly asymmetrical mixtures. This is the first report that shows a prediction of the thermophoretic velocities of uncharged colloids. The relation between the thermophoretic mobility of colloids and the Hamaker constant of the solute–solvent interactions enables an experimental determination of the latter quantity from thermophoresis data.