AuB8−: an Au–borozene complex

AuB8−: an Au–borozene complex

Photoelectron spectroscopy and quantum chemistry studies are used to investigate the structure and bonding of AuB8−. Global minimum sturctural searches show that AuB8− possesses a chair-like structure, which can be viewed as Au+ bonded to the edge of the doubly-aromatic B82− borozene, Au+[η2-B82−]....

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (19), p.3134-3137
Hauptverfasser: Wei-Jia, Chen, Yang-Yang, Zhang, Wan-Lu, Li, Choi, Hyun Wook, Li, Jun, Lai-Sheng, Wang
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Photoelectrons
Quantum chemistry
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Zusammenfassung:Photoelectron spectroscopy and quantum chemistry studies are used to investigate the structure and bonding of AuB8−. Global minimum sturctural searches show that AuB8− possesses a chair-like structure, which can be viewed as Au+ bonded to the edge of the doubly-aromatic B82− borozene, Au+[η2-B82−]. Chemical bonding analyses reveal that the AuB8− is a novel borozene complex with unique Au–borozene bonding.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc07303f