ESR STUDY OF FREE RADICALS IN IRRADIATED POLYAMIDE-1010
Polyamide-1010 samples were irradiated in vacuum at room temperature by Cobalt-60 γ-rays. The free radicals formed in irradiation were studied by means of electron spin resonance （ESR）techniques.The ESRspectra consisted of a quartet and a superimposed singlet which were attributed to radical -CO-NH-...
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| Veröffentlicht in: | Chinese journal of polymer science 1993, Vol.11 (1), p.46-53 |
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| Format: | Artikel |
| Sprache: | eng |
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| Zusammenfassung: | Polyamide-1010 samples were irradiated in vacuum at room temperature by Cobalt-60 γ-rays. The free radicals formed in irradiation were studied by means of electron spin resonance （ESR）techniques.The ESRspectra consisted of a quartet and a superimposed singlet which were attributed to radical -CO-NH-CH-CH2 and -CH2-C=O, respectively. The effects of temperature and crystaUinity on the radicals were discussed and the mechanism for the production and decay of the radicals was also proposed. |
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| ISSN: | 0256-7679 1439-6203 |