Aspects of rhodium marine chemistry

Rhodium, one of the least abundant of the Pt-group elements in the earth's crust, has the second highest concentration in seawater. This may be a consequence of strong complexing, perhaps kinetically restrained with time constants of the order of centuries to millenia. The element shows a nutri...

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Veröffentlicht in:Marine chemistry 1993, Vol.42 (3), p.199-210
Hauptverfasser: Bertine, Kathe K., Koide, Minoru, Goldberg, Edward D.
Format: Artikel
Sprache:eng
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Zusammenfassung:Rhodium, one of the least abundant of the Pt-group elements in the earth's crust, has the second highest concentration in seawater. This may be a consequence of strong complexing, perhaps kinetically restrained with time constants of the order of centuries to millenia. The element shows a nutrient-like distribution in waters of the Pacific Ocean. Pelagic and coastal sediments have Rh concentrations close to crustal values. There is a remarkable enrichment of Rh in ferromanganese minerals that cannot be explained by oxidative capture. Unlike the other Pt-group elements, Rh is enriched in the high temperature hydrothermal sulfide deposits as well as phosphorites.
ISSN:0304-4203
1872-7581
DOI:10.1016/0304-4203(93)90012-D