Pd-Catalyzed Regioselective Branched Hydrocarboxylation of Terminal Olefins with Formic Acid

Pd-Catalyzed Regioselective Branched Hydrocarboxylation of Terminal Olefins with Formic Acid

A regioselective Pd-catalyzed hydrocarboxylation of terminal olefins with HCOOH is described. A wide variety of branched carboxylic acids can readily be obtained with high regioselectivities under mild reaction conditions. The reaction is operationally simple and requires no handling of toxic CO. Th...

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Veröffentlicht in:Organic letters 2022-01, Vol.24 (3), p.886-891
Hauptverfasser: Ren, Wenlong, Wang, Mingzhou, Guo, Jianqiong, Zhou, Jintao, Chu, Jianxiao, Shi, Yuan, Shi, Yian
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container_issue 3
container_start_page 886
container_title Organic letters
container_volume 24
creator Ren, Wenlong
Wang, Mingzhou
Guo, Jianqiong
Zhou, Jintao
Chu, Jianxiao
Shi, Yuan
Shi, Yian
description A regioselective Pd-catalyzed hydrocarboxylation of terminal olefins with HCOOH is described. A wide variety of branched carboxylic acids can readily be obtained with high regioselectivities under mild reaction conditions. The reaction is operationally simple and requires no handling of toxic CO. The ligand and LiCl are important factors for reaction reactivity and selectivity.
doi_str_mv 10.1021/acs.orglett.1c04231
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title Pd-Catalyzed Regioselective Branched Hydrocarboxylation of Terminal Olefins with Formic Acid
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