Synthesis of Octachloro- and Octaazido-Functionalized T8‑Cages and Application to Recyclable Palladium Catalyst

Unprecedented T8-cages bearing eight chloromethyldimethylsilylethyl substituents were obtained in excellent yield from the readily and commercially available octavinylsilsesquioxane. The chloro groups can be quantitatively substituted by azido ones to yield the corresponding octaazido T8 without rea...

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Veröffentlicht in:	Inorganic chemistry 2022-01, Vol.61 (3), p.1495-1503
Hauptverfasser:	Liu, Yujia, Koizumi, Kyoka, Takeda, Nobuhiro, Unno, Masafumi, Ouali, Armelle
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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