Deconvolution and spectral clean-up of two-component mixtures by factor analysis of gas chromatographic-mass spectrometric data
Binary mixtures of closely eluting and spectroscopically similar compounds were used as an example to test the deconvolution of GC-MS data, using 2 datasets. In set 1, the components are well resolved, but in set 2, one peak is broadened so that there is complete overlap. The method is shown to work...
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| Veröffentlicht in: | Analyst (London) 1996, Vol.121 (8), p.993-1001 |
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| container_title | Analyst (London) |
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| creator | HINDMARCH, P DEMIR, C BRERETON, R. G |
| description | Binary mixtures of closely eluting and spectroscopically similar compounds were used as an example to test the deconvolution of GC-MS data, using 2 datasets. In set 1, the components are well resolved, but in set 2, one peak is broadened so that there is complete overlap. The method is shown to work well even when there is no selectivity in the chromatographic direction. (Abstract quotes from original text) |
| doi_str_mv | 10.1039/AN9962100993 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0003-2654 |
| ispartof | Analyst (London), 1996, Vol.121 (8), p.993-1001 |
| issn | 0003-2654 1364-5528 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26123283 |
| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Analysis Analytical chemistry Biological and medical sciences Chemistry Chromatographic methods and physical methods associated with chromatography Exact sciences and technology Gas chromatographic methods General pharmacology Medical sciences Pharmacology. Drug treatments |
| title | Deconvolution and spectral clean-up of two-component mixtures by factor analysis of gas chromatographic-mass spectrometric data |
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