Soft Organic Thermoelectric Materials: Principles, Current State of the Art and Applications

The enormous demand for waste heat utilization and burgeoning eco‐friendly wearable materials has triggered huge interest in the development of thermoelectric materials that can harvest low‐cost energy resources by converting waste heat to electricity efficiently. In particular, due to their high flexibility, nontoxicity, cost‐effectivity, and promising applicability in various fields, organic thermoelectric materials are drawing more attention compared with their toxic, expensive, heavy, and brittle inorganic counterparts. Organic thermoelectric materials are approaching the figure of merit of the inorganic ones via the construction and optimization of unique transport pathways and device geometries. This review presents the recent development of the interdependence and decoupling principles of the thermoelectric efficiency parameters as well as the new achievements of high performance organic thermoelectric materials. Moreover, this review also discusses the advances in the thermoelectric devices with emphasis on their energy‐related applications. It is believed that organic thermoelectric materials are emerging as green energy alternatives rivaling their conventional inorganic counterparts in the efficient and pure electricity harvesting from waste heat and solar thermal energy. Organic thermoelectric materials are approaching the figure of merit of the inorganic ones via the construction and optimization of unique transport pathways and device geometries. This review summarizes recent studies of organic thermoelectric materials, discusses their progress and the underlying mechanisms, and envisions an outlook for their future development.