Pyrite-embedded porous carbon nanocatalysts assembled in polyvinylidene difluoride membrane for organic pollutant oxidation

[Display omitted] FeS2-embedded in porous carbon (FeS2/C) was prepared by simultaneous sulfidation and carbonization of an iron-based metal–organic framework precursor, and subsequently immobilized in polyvinylidene fluoride membranes (FeS2/C@PVDF) for organics removal via peroxymonosulfate (PMS) activation. The composition, structure, and morphology of the FeS2/C@PVDF membrane were extensively characterized. Scanning electron microscopy images manifest that the FeS2/C nanoparticles with an average diameter of 40 nm are assembled on the external and internal membrane surface. The as-prepared FeS2/C@PVDF membrane exhibits excellent performances over a wide pH range of 1.53–9.50, exceeding carbon-free syn-FeS2@PVDF. The effective degradation could be improved by inner pyrite FeS2 cores and thus enhanced the electron transfer between carbon shell and PMS. Electron paramagnetic resonance and quenching experiments elucidated that radical (HO∙, SO4∙-) and nonradical (1O2) species were the predominant reactive oxidants. In addition, FeS2/C@PVDF exhibited high stability with low Fe leaching (0.377 mg/L) owing to the effective protection of the outer carbon skeleton. Plentiful porosity of PVDF membranes not only affords a controlled size and confined uniform distribution of the immobilized FeS2/C nanoparticles, but also enables a persistent exposure of active sites and enhanced mass transfer efficiency. Our findings demonstrate a promise for utilizing the novel FeS2/C@PVDF membrane as an efficient catalyst for the environmental cleanup.