Boosting Oxygen Reduction Activity of Manganese Oxide Through Strain Effect Caused By Ion Insertion

Transition‐metal oxides with a strain effect have attracted immense interest as cathode materials for fuel cells. However, owing to the introduction of heterostructures, substrates, or a large number of defects during the synthesis of strain‐bearing catalysts, not only is the structure–activity relationship complicated but also their performance is mediocre. In this study, a mode of strain introduction is reported. Transition‐metal ions with different electronegativities are intercalated into the cryptomelane‐type manganese oxide octahedral molecular sieves (OMS‐2) structure with K ions as the template, resulting in the octahedral structural distortion of MnO6 and producing strains of different degrees. Experimental studies reveal that Ni‐OMS‐2 with a high compressive strain (4.12%) exhibits superior oxygen reduction performance with a half‐wave potential (0.825 V vs RHE) greater than those of other reported manganese‐based oxides. This result is related to the increase in the covalence of MnO6 octahedral configuration and shifting down of the eg band center caused by the higher compression strain. This research avoids the introduction of new chemical bonds in the main structure, weakens the effect of eg electron filling number, and emphasizes the pure strain effect. This concept can be extended to other transition‐metal‐oxide catalysts. The tunnel structure is skillfully used to adjust the strain of manganese oxide octahedral molecular sieves, enduing OMS‐2 with unprecedented catalytic activity. Furthermore, the effect of pure strain on covalency and eg band center is also discussed. The higher compression strain increases the covalence of MnO6 octahedral configuration and moves down the eg band center, thereby benefiting the interaction between active substance and oxygen intermediates.