Determination of interfacial tensions between BPA polycarbonate and styrene-acrylonitrile copolymers from capillary thread instability measurements

The interfacial tensions between BPA polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) blends having S/AN ratios varying between 100 0 and 60 40 (wt%) have been determined by measuring capillary thread breakup rates at 200°C. A distinct minimum in the interfacial tension is observed clo...

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Veröffentlicht in:Polymer (Guilford) 1993-01, Vol.34 (18), p.3955-3959
Hauptverfasser: Watkins, V.H., Hobbs, S.Y.
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description The interfacial tensions between BPA polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) blends having S/AN ratios varying between 100 0 and 60 40 (wt%) have been determined by measuring capillary thread breakup rates at 200°C. A distinct minimum in the interfacial tension is observed close to the SAN composition reported to show maximum miscibility with PC. For the case of PC/PS, the measured values are compared with those calculated from published studies on PS/poly methyl methacrylate (PMMA) and PC/PMMA.
doi_str_mv 10.1016/0032-3861(93)90527-H
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source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Exact sciences and technology
interfacial tension
Organic polymers
Physicochemistry of polymers
polycarbonate
Properties and characterization
SAN copolymers
Surface properties
title Determination of interfacial tensions between BPA polycarbonate and styrene-acrylonitrile copolymers from capillary thread instability measurements
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