Determination of interfacial tensions between BPA polycarbonate and styrene-acrylonitrile copolymers from capillary thread instability measurements

The interfacial tensions between BPA polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) blends having S/AN ratios varying between 100 0 and 60 40 (wt%) have been determined by measuring capillary thread breakup rates at 200°C. A distinct minimum in the interfacial tension is observed clo...

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Veröffentlicht in:Polymer (Guilford) 1993-01, Vol.34 (18), p.3955-3959
Hauptverfasser: Watkins, V.H., Hobbs, S.Y.
Format: Artikel
Sprache:eng
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Zusammenfassung:The interfacial tensions between BPA polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) blends having S/AN ratios varying between 100 0 and 60 40 (wt%) have been determined by measuring capillary thread breakup rates at 200°C. A distinct minimum in the interfacial tension is observed close to the SAN composition reported to show maximum miscibility with PC. For the case of PC/PS, the measured values are compared with those calculated from published studies on PS/poly methyl methacrylate (PMMA) and PC/PMMA.
ISSN:0032-3861
1873-2291
DOI:10.1016/0032-3861(93)90527-H