Silole allylic anions instead of silanides
Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KO t Bu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighboring phenyl group, which th...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-11, Vol.5 (46), p.16945-16949 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KO
t
Bu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighboring phenyl group, which then transfers a proton to the 2-position of the silole ring.
The reactions of 3,4-diphenylsiloles with two neopentasilanyl groups in 2- and 5-positions with one equivalent of KO
t
Bu do not yield the expected silanides but silole allylic anions instead. |
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ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/d1dt02363b |