Silole allylic anions instead of silanides

Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KO t Bu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighboring phenyl group, which th...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2021-11, Vol.5 (46), p.16945-16949
Hauptverfasser: Pöcheim, Alexander, Albers, Lena, Müller, Thomas, Baumgartner, Judith, Marschner, Christoph
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KO t Bu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighboring phenyl group, which then transfers a proton to the 2-position of the silole ring. The reactions of 3,4-diphenylsiloles with two neopentasilanyl groups in 2- and 5-positions with one equivalent of KO t Bu do not yield the expected silanides but silole allylic anions instead.
ISSN:1477-9226
1477-9234
DOI:10.1039/d1dt02363b