Recent progress of preparation of branched poly(lactic acid) and its application in the modification of polylactic acid materials

Poly (lactic acid) (PLA) with branched structure has abundant terminal groups, high melt strength, good rheological properties, and excellent processability; it is a new research and application direction of PLA materials. This study mainly summarizes the molecular structure design, preparation methods, basic properties of branched PLA, and its application in modified PLA materials. The structure and properties of branched PLA prepared by ring-opening polymerization of monomer, functional group polycondensation, and chain extender in the processing process were introduced. The research progress of in situ formation of branched PLA by initiators, multifunctional monomers/additives through dynamic vulcanization, and irradiation induction was described. The effect of branched PLA on the structure and properties of linear PLA materials was analyzed. The role of branched PLA in improving the crystallization behavior, phase morphology, foaming properties, and mechanical properties of linear PLA materials was discussed. At the same time, its research progress in biomedicine and tissue engineering was analyzed. Branched PLA has excellent compatibility with PLA, which has important research value in regulating the structure and properties of PLA materials. •Branched PLA has important research value in regulating the structure and properties of PLA materials.•Branched PLA prepared by ROP, functional group polycondensation and chain extension was introduced.•Branched PLA produced in situ by dynamic vulcanization and radiation-induced reaction was discussed.•The role of branched PLA in improving the crystallization, compatibility, foaming and mechanical properties was discussed.•The research progress of branched PLA in biomedicine and tissue engineering was analyzed.