Humidity‐Induced Defect‐Healing of Formamidinium‐Based Perovskite Films

Formamidinium (FA)‐based perovskite material holds great potential to deliver highly efficient commercial solar cells. However, the FA‐based perovskite films are commonly processed under a strictly controlled environment, which would eventually hinder their way to commercialization. Herein, a systematic study is conducted to investigate the sequential deposition of FA‐based perovskite films that are annealed under ambient conditions. Unexpectedly, the films prepared in low humidity condition possess less pinholes and defects and exhibit better device performances than those prepared in the moisture‐free condition. A series of in situ and ex situ investigations are conducted which reveal defects in perovskite films are continuously healed during the film annealing process under the humid condition. This extraordinary effect is attributed to the interaction between water molecules and perovskite. The current study should shed light on the ambient fabrication of FA‐based perovskite solar cells and foster their real‐world applications. The formamidinium‐based perovskite films prepared in the low humidity condition possess less pinholes and defects and exhibit better device performances than those prepared in the moisture‐free condition. The defects in the perovskite films are continuously healed during thermal annealing through the interaction between water molecules and perovskite.