Role of selected cations and gas speciation on the reduction of fayalite at 1300 degrees C
The role of cation additives in reduction with CO-rich gases is minimally important. In H-rich reduction studies, the reduction per hour is increased 50% by a 2.5 wt% addition of CaO, increased approximately 75% by a 2.5 wt% addition of Cr sub 2 O sub 3 , and increased approximately 50% for a 2.5 wt...
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Veröffentlicht in: | Journal of the American Ceramic Society 1992-06, Vol.75 (6), p.1476-1483 |
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description | The role of cation additives in reduction with CO-rich gases is minimally important. In H-rich reduction studies, the reduction per hour is increased 50% by a 2.5 wt% addition of CaO, increased approximately 75% by a 2.5 wt% addition of Cr sub 2 O sub 3 , and increased approximately 50% for a 2.5 wt% addition of MnO as compared to the reduction rate of pure fayalite liquid. More dramatic than any cation additive effect is the role of H content of the gas mixture. At 1300 degrees C and a fixed - log fO sub 2 =13, the reduction per h of pure fayalite liquid triples with the replacement of CO by H, even with just the first 10 vol% of H. 36 refs. |
doi_str_mv | 10.1111/j.1151-2916.1992.tb04213.x |
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At 1300 degrees C and a fixed - log fO sub 2 =13, the reduction per h of pure fayalite liquid triples with the replacement of CO by H, even with just the first 10 vol% of H. 36 refs.</description><identifier>ISSN: 0002-7820</identifier><identifier>DOI: 10.1111/j.1151-2916.1992.tb04213.x</identifier><language>eng</language><ispartof>Journal of the American Ceramic Society, 1992-06, Vol.75 (6), p.1476-1483</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ulmer, Gene C</creatorcontrib><title>Role of selected cations and gas speciation on the reduction of fayalite at 1300 degrees C</title><title>Journal of the American Ceramic Society</title><description>The role of cation additives in reduction with CO-rich gases is minimally important. 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In H-rich reduction studies, the reduction per hour is increased 50% by a 2.5 wt% addition of CaO, increased approximately 75% by a 2.5 wt% addition of Cr sub 2 O sub 3 , and increased approximately 50% for a 2.5 wt% addition of MnO as compared to the reduction rate of pure fayalite liquid. More dramatic than any cation additive effect is the role of H content of the gas mixture. At 1300 degrees C and a fixed - log fO sub 2 =13, the reduction per h of pure fayalite liquid triples with the replacement of CO by H, even with just the first 10 vol% of H. 36 refs.</abstract><doi>10.1111/j.1151-2916.1992.tb04213.x</doi><tpages>8</tpages></addata></record> |
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title | Role of selected cations and gas speciation on the reduction of fayalite at 1300 degrees C |
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