Role of selected cations and gas speciation on the reduction of fayalite at 1300 degrees C

The role of cation additives in reduction with CO-rich gases is minimally important. In H-rich reduction studies, the reduction per hour is increased 50% by a 2.5 wt% addition of CaO, increased approximately 75% by a 2.5 wt% addition of Cr sub 2 O sub 3 , and increased approximately 50% for a 2.5 wt...

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Veröffentlicht in:Journal of the American Ceramic Society 1992-06, Vol.75 (6), p.1476-1483
1. Verfasser: Ulmer, Gene C
Format: Artikel
Sprache:eng
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Zusammenfassung:The role of cation additives in reduction with CO-rich gases is minimally important. In H-rich reduction studies, the reduction per hour is increased 50% by a 2.5 wt% addition of CaO, increased approximately 75% by a 2.5 wt% addition of Cr sub 2 O sub 3 , and increased approximately 50% for a 2.5 wt% addition of MnO as compared to the reduction rate of pure fayalite liquid. More dramatic than any cation additive effect is the role of H content of the gas mixture. At 1300 degrees C and a fixed - log fO sub 2 =13, the reduction per h of pure fayalite liquid triples with the replacement of CO by H, even with just the first 10 vol% of H. 36 refs.
ISSN:0002-7820
DOI:10.1111/j.1151-2916.1992.tb04213.x