Fabrication of carbon dots for sequential on–off-on determination of Fe3+ and S2− in solid-phase sensing and anti-counterfeit printing

Glutathione and 2-aminopyridine are used as carbon sources to prepare carbon dots (CDs) by a one-step hydrothermal reaction. The results show that the average particle diameter of CDs is 8.64 nm with uniform size distribution and the fluorescence quantum yield is 13.62%. We further demonstrate that novel CDs possess highly selective sensing of Fe 3+ from 0.2 to 200 μM with a low detection limit (0.194 μM). Meanwhile, the fluorescence of CDs can be repeated many times by the addition of S 2− . Moreover, the CDs are used for biological imaging of living cells with well cell penetrability and low toxicity. Furthermore, it is successfully applied for anti-counterfeiting and information encryption. More interestingly, it can be doped with hydrogel and filter paper to prepare solid-phase sensors exhibiting high sensitivity and fast response, demonstrating their tremendous potential for the simple, rapid, and low-cost monitoring of Fe 3+ and S 2− . Graphical abstract