Photointercalation effect of thin WO3 films

It is shown that thin amorphous films of WO3 exhibit a photoinduced reversible coloration in an electrochemical cell of the form quartz/semitransparent Au/ethanol/WO3/In2O3-coated glass. From measurements of the optical and electrical properties of the films, the coloration is attributed to the form...

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Veröffentlicht in:Applied physics letters 1990-09, Vol.57 (13), p.1324-1325
Hauptverfasser: Nagasu, Masahiro, Koshida, Nobuyoshi
Format: Artikel
Sprache:eng
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Zusammenfassung:It is shown that thin amorphous films of WO3 exhibit a photoinduced reversible coloration in an electrochemical cell of the form quartz/semitransparent Au/ethanol/WO3/In2O3-coated glass. From measurements of the optical and electrical properties of the films, the coloration is attributed to the formation of HxWO3, presumably due to a photointercalation of protons into WO3 films. This effect is potentially useful for storage, learning, and modulation of two-dimensional optical information.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.104231