Phyllosilicate derived catalysts for efficient conversion of lignocellulosic derived biomass to biodiesel: A review

•Phyllosilicate catalysts for lignocellulosic biomass conversion to biofuels.•Phyllosilicate minerals exhibit higher potential for synthesis of efficient catalyst.•Recent methodologies for development of catalyst have been critically reviewed.•Catalytic potential of phyllosilicate derived catalysts has been presented.•Investigation on lignocellulosic biomass resources using phyllosilicate is needed. The efforts have been made to review phyllosilicate derived (clay-based) heterogeneous catalysts for biodiesel production via lignocellulose derived feedstocks. These catalysts have many practical and potential applications in green catalysis. Phyllosilicate derived heterogeneous catalysts (modified via any of these approaches like acid activated clays, ion exchanged clays and layered double hydroxides) exhibits excellent catalytic activity for producing cost effective and high yield biodiesel. The combination of different protocols (intercalated catalysts, ion exchanged catalysts, acidic activated clay catalysts, clay-supported catalysts, composites and hybrids, pillared interlayer clay catalysts, and hierarchically structured catalysts) was implemented so as to achieve the synergetic effects (acidic-basic) in resultant material (catalyst) for efficient conversion of lignocellulose derived feedstock (non-edible oils) to biodiesel. Utilisation of these Phyllosilicate derived catalysts will pave path for future researchers to investigate the cost-effective, accessible and improved approaches in synthesising novel catalysts that could be used for converting lignocellulosic biomass to eco-friendly biodiesel.