Sixteen priority polycyclic aromatic hydrocarbons in roadside soils at traffic light intersections (Bratislava, Slovakia): concentrations, sources and influencing factors

Combustion of fossil fuels is the most important source of polycyclic aromatic hydrocarbons (PAHs) in the environment. Cities are typical of many human activities which are dependent on fossil fuels (road and railway transport, heat generation, waste incineration and industry) on a small area, leading to high concentrations of PAHs in urban air, dust and soil. The aim of this study was to determine the possible influence of urban traffic on the accumulation of sixteen priority PAHs in soils ( n = 132 at two soil depths of 0–10 cm and 10–20 cm) taken at intersections ( n = 37) with different traffic volumes and road ages. Variable concentrations of the sum of PAHs (∑ 16 PAH) ranging from 188 to 21,950 μg/kg with a mean and median of 3021 μg/kg and 1930 μg/kg were recorded, respectively. Concentrations of PAHs positively correlated with soil organic carbon content (TOC) ( r Spearman = 0.518; p