Application of lead oxide electrodes in wastewater treatment: A review

Electrochemical oxidation (EO) based on hydroxyl radicals (·OH) generated on lead dioxide has become a typical advanced oxidation process (AOP). Titanium-based lead dioxide electrodes (PbO2/Ti) play an increasingly important role in EO. To further improve the efficiency, the structure and properties of the lead dioxide active surface layer can be modified by doping transition metals, rare earth metals, nonmetals, etc. Here, we compare the common preparation methods of lead dioxide. The EO performance of lead dioxide in wastewater containing dyes, pesticides, drugs, landfill leachate, coal, petrochemicals, etc., is discussed along with their suitable operating conditions. Finally, the factors influencing the contaminant removal kinetics on lead dioxide are systematically analysed. [Display omitted] •The commonly used methods of preparing lead dioxide coatings are compared in detail.•Dopants improve electrocatalytic activity by increasing the active surface sites.•A standardized method to evaluate the effectiveness of lead dioxide is needed.•The structural changes of lead dioxide in the catalytic process are poorly studied.