Green electrospinning of chitin propionate to manufacture nanofiber mats

Chitin is the second most abundant biopolymer after cellulose in nature, and it is currently under-utilized partially because of its insolubility in common solvents. Herein, chitin was propionylated to improve its dissolution in green solvents, i.e., ethanol and water, and manufactured nanofibers and nonwoven mats via electrospinning with poly(ethylene oxide) (PEO) as a co-spinning aid. Polymer solution viscosity, electrospun CP/PEO fiber morphology, mechanical, thermal, dynamic thermal, and surface contact angle of nanofiber mats were evaluated. Results showed that fibers with CP content up to 97% could be produced. The electrospun CP/PEO nanofiber mats exhibited good mechanical strength, thermal stability, and hydrophobicity with water contact angles up to 133°. Filtration test of separating carbon nanofibers and carbon nanotubes from water demonstrated the potential use of the CP/PEO nanofiber mats in fluid filtration of fibrous pollutants. [Display omitted] •Chitin propionate dissolves in ethanol and water mixtures.•Chitin propionate can be electrospun into nanofibers with a small amount of spinning aid.•The nanofiber mats electrospun from chitin nanofibers exhibit great mechanical modulus and strength.•Chitin nanofiber mat is hydrophobic with water contact angle up to 133°.•Chitin nanofiber mat demonstrates good filtration efficiency.