Seasonal and Diurnal Variations of BTEX in Ambient Air from a Site Impacted by the Oil Industry in Southeast Mexico

Atmospheric concentrations of BTEX were measured in an urban site located in the vicinity of an oil storage-distribution facility in Paraiso, Tabasco, Mexico. Samples were collected during two seasons (nortes 2018 and dry 2019). The relative abundance of BTEX mean concentrations was: toluene (5.24 µg m −3 ) > ethylbenzene (3.92 µg m −3 ) > m, p-xylene (3.89 µg m −3 ) > benzene (2.43 µg m −3 ). BTEX concentrations had a clear diurnal and seasonal pattern, showing higher levels during the dry season due to differences in wind conditions, rainfall patterns and temperature. Statistical analysis showed significant positive correlations among BTEX, indicating that these compounds had common sources. Interspecies ratios revealed that BTEX were originated from sources beyond vehicular traffic and that they were influenced by the transport of local air masses. The assessment of lifetime cancer risk showed that the population in the study area is at possible risk of developing cancer.