Pentanuclear Thorium(IV) Coordination Cluster from the Use of Di(2-pyridyl) Ketone

Pentanuclear Thorium(IV) Coordination Cluster from the Use of Di(2-pyridyl) Ketone

The Th­(NO3)4·5H2O/di­(2-pyridyl) ketone [(py)2CO] reaction system gives a pentanuclear cluster containing the doubly deprotonated form of the gem-diol derivative of the ligand. The cluster consists of a tetrahedral arrangement of four ThIV ions centered on the fifth ion, which is the first characte...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2021-08, Vol.60 (16), p.11888-11892
Hauptverfasser: Tsantis, Sokratis T, Danelli, Panagiota, Tzimopoulos, Demetrios I, Raptopoulou, Catherine P, Psycharis, Vassilis, Perlepes, Spyros P
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The Th­(NO3)4·5H2O/di­(2-pyridyl) ketone [(py)2CO] reaction system gives a pentanuclear cluster containing the doubly deprotonated form of the gem-diol derivative of the ligand. The cluster consists of a tetrahedral arrangement of four ThIV ions centered on the fifth ion, which is the first characterized ThIV 5 complex. The analysis of its structure reveals that this is a Kuratowski-type coordination compound.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c01800