4p-4d Fano-like resonance in rhodium

Photoemission measurements of Rh films in the photon energy range 40-120 eV show that the 4p-4d intrashell interaction has a Fano-like resonance. The 4d photoemission intensity goes through a sharp dip in the vicinity of the 4p exp 6 4d exp n + h nu - > 4p exp 5 4d exp n+1 threshold followed by a...

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Veröffentlicht in:Journal of electron spectroscopy and related phenomena 1990-05, Vol.50 (3), p.195-200
Hauptverfasser: MURGAI, V, YOUNG-SEA HUANG, RUCKMAN, M. W, RAAEN, S
Format: Artikel
Sprache:eng
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Zusammenfassung:Photoemission measurements of Rh films in the photon energy range 40-120 eV show that the 4p-4d intrashell interaction has a Fano-like resonance. The 4d photoemission intensity goes through a sharp dip in the vicinity of the 4p exp 6 4d exp n + h nu - > 4p exp 5 4d exp n+1 threshold followed by a resonant enhancement before decreasing again. All parts of the 4d band show the same resonant behaviour in contrast to previous resonant photoemission results. The resonant behaviour of Rh is compared with Co which is the 3d analog of Rh. Spectra. 14 ref.--AA
ISSN:0368-2048
1873-2526
DOI:10.1016/0368-2048(90)87063-T