Theme and variations on tantalum-carbonate reactions in molten fluorides

Fluorotantalate and carbonate ions react to form CO sub 2 , but the reaction is incomplete and remaining carbonate is reduced to form carbide. Kinetics and thermodynamics are discussed.

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Veröffentlicht in:Journal of the Electrochemical Society 1989-12, Vol.136 (12), p.3760-3767
Hauptverfasser: STERN, K. H, ROLISON, D. R
Format: Artikel
Sprache:eng
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Zusammenfassung:Fluorotantalate and carbonate ions react to form CO sub 2 , but the reaction is incomplete and remaining carbonate is reduced to form carbide. Kinetics and thermodynamics are discussed.
ISSN:0013-4651
1945-7111
DOI:10.1149/1.2096543