The geochemistry and hydrology of coal waste rock dumps: A systematic global review

Coal has been a major global resource for at least the past 250 years. The major waste product of coal mining is waste rock, which is stored in dumps of various sizes. Although the adverse effects of coal waste rock dumps on ecosystems and human health are widely recognised, there is little information on their internal hydrological and geochemical processes in the peer-reviewed literature. Coal and conventional waste rock dumps share many similarities, but coal waste rock dumps differ in structure, organic matter content, and size, which can affect the timing and rate of aqueous chemical release. In this global systematic review, we identify limited links to climate setting and dump construction, and inconsistent reporting of sampling and monitoring approaches, as limitations to the generalisation of findings. Furthermore, sources of aqueous constituents of interest (COIs) are not routinely or adequately identified, which can lead to incorrect assumptions regarding COI availability and geochemical mobility. Water flow regimes within dumps are dominated by matrix and/or preferential flow, depending on dump texture; these flow mechanisms exert a primary control on patterns of aqueous COI release. The inability to successfully transfer COI release rates from laboratory or field scale trials to operational scale dumps is primarily due to limitations of testing methods and fundamental characteristics of scale. Prediction of future release rates is hampered by a lack of long-term studies that fully characterise geochemistry (e.g., source and COI production rates) as well as dump hydrology (e.g., water balance, water migration). Five critical elements to include in best practice investigations are climate setting, dump physical characteristics, geochemical processes, water regime, and environmental load over time, as aqueous release of COIs from coal waste rock dumps occurs over decades to centuries. Key considerations are identified for each of these elements to guide best practice. [Display omitted] •Mechanistic understanding of hydrology and geochemistry limited by characterisation•Oxidation controls reactive contaminant transport; hydrology controls non-reactive•Internal geochemical sinks alter the general controls on contaminant transport•Combustion changes geochemical processes; effect on hydrology unknown•Need long-term data to assess temporal changes to aqueous contaminant export