Recent Progress in External‐Stimulus‐Responsive 2D Covalent Organic Frameworks

Recently, smart 2D covalent organic frameworks (COFs), combining the advantages of both inherent structure features and functional building blocks, have been demonstrated to show reversible changes in conformation, color, and luminescence in response to external stimuli. This review provides a summa...

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Veröffentlicht in:Advanced materials (Weinheim) 2022-06, Vol.34 (22), p.e2101175-n/a
Hauptverfasser: She, Pengfei, Qin, Yanyan, Wang, Xiang, Zhang, Qichun
Format: Artikel
Sprache:eng
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Zusammenfassung:Recently, smart 2D covalent organic frameworks (COFs), combining the advantages of both inherent structure features and functional building blocks, have been demonstrated to show reversible changes in conformation, color, and luminescence in response to external stimuli. This review provides a summary on the recent progress of 2D COFs that are responsive to external stimuli such as metal ions, gas molecules, pH values, temperature, electricity, light, etc. Moreover, the responsive mechanisms and design strategies, along with the applications of these stimulus‐responsive 2D COFs in chemical sensors and photoelectronic devices are also discussed. It is believed that this review would provide some guidelines for designing novel single‐/multistimulus‐responsive 2D COFs with controllable responsive behaviors for advanced photoelectronic applications. In this review, the recent process of stimulus‐responsive 2D covalent organic frameworks (COFs) is summarized. The responsive behaviors and design strategies of these smart 2D COFs under physical or chemical stimuli are well described. Moreover, their applications in chemical sensors and photoelectronic devices are also discussed.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.202101175