Recent advances in structural modifications of photo-catalysts for organic pollutants degradation – A comprehensive review

Over the last few years, industrial and anthropogenic activities have increased the presence of organic pollutants such as dyes, herbicides, pesticides, analgesics, and antibiotics in the water that adversely affect human health and the environment worldwide. Photocatalytic treatment is considered a promising, economical, effective, and sustainable process that utilizes light energy to degrade the pollutants in water. However, certain drawbacks like rapid recombination and low migration capability of photogenerated electrons and holes have restricted the use of photo-catalysts in industries. Hence, despite the abundance of lab-scale research, the technology is still not much commercialized in the mainstream. Several structural modifications in the photo-catalysts have been adopted to enhance the pollutant degradation performance to overcome the same. In this context, the present review article outlines the different advanced heterostructures synthesized to date for improved degradation of three major organic pollutants: antibiotics, dyes, and pesticides. Moreover, the article also emphasizes the degradation kinetics of photo-catalysts and the publication trend in the past decade along with the roadblocks preventing the transfer of technology from the laboratory to industry and new age photo-catalysts for the profitable implications in industrial sectors. [Display omitted] •Photocatalytic degradation of three major organic pollutants: antibiotics, pesticides and dyes are reviewed.•Modification strategies are described that may be adopted to enhance the degradation efficiency of photocatalyst.•The trends in publications on various photocatalysts from the past decade are scrutinized.•The work spotlights the rationale behind lack of transfer of technology from lab to industry.