Flexible Phase Change Materials for Electrically‐Tuned Active Absorbers

Phase change materials (PCMs), such as GeSbTe (GST) alloys and vanadium dioxide (VO2), play an important role in dynamically tunable optical metadevices. However, the PCMs usually require high thermal annealing temperatures above 700 K, but most flexible metadevices can only work below 500 K owing to the thermal instability of polymer substrates. This contradiction limits the integration of PCMs into flexible metadevices. Here, a mica sheet is chosen as the chemosynthetic support for VO2 and a smooth and uniformly flexible phase change material (FPCM) is realized. Such FPCMs can withstand high temperatures while remaining mechanically flexible. As an example, a metal‐FPCM‐metal infrared meta‐absorber with mechanical flexibility and electrical tunability is demonstrated. Based on the electrically‐tuned phase transition of FPCMs, the infrared absorption of the metadevice is continuously tuned from 20% to 90% as the applied current changes, and it remains quite stable at bending states. The metadevice is bent up to 1500 times, while no visible deterioration is detected. For the first time, the FPCM metastructures are significantly added to the flexible material family, and the FPCM‐based metadevices show various application prospects in electrically‐tunable conformal metadevices, dynamic flexible photodetectors, and active wearable devices. In this work, a smooth and uniformly flexible phase change material (FPCM) is realized based on vanadium dioxide (VO2). As an example, a metal‐FPCM‐metal infrared meta‐absorber with mechanical flexibility and electrical tunability is demonstrated. It is expected that such FPCM‐based metadevices would show various application prospects in dynamic flexible photodetectors and active wearable devices.