Poly(vinyl phenol)—polyether blends

Spinodal phase diagram calculations are presented for poly(vinyl phenol)—polyether blends. Equilibrium constants corresponding to self-association and inter-association were transferred from those reported in the literature for low molecular weight model analogues after adjusting to account for diff...

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Veröffentlicht in:	Polymer (Guilford) 1991-01, Vol.32 (3), p.516-522
Hauptverfasser:	Serman, Carl J., Xu, Yun, Painter, Paul C., Coleman, Michael M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology infra-red studies miscibility Organic polymers phase diagrams Physicochemistry of polymers poly(vinyl ethers) poly(vinyl phenol) polymer blends Properties and characterization specific interactions Thermal and thermodynamic properties
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Beschreibung
Zusammenfassung:	Spinodal phase diagram calculations are presented for poly(vinyl phenol)—polyether blends. Equilibrium constants corresponding to self-association and inter-association were transferred from those reported in the literature for low molecular weight model analogues after adjusting to account for differences in molar volume of the model and the polymer repeat. The results are in good agreement with the trends observed experimentally.
ISSN:	0032-3861 1873-2291
DOI:	10.1016/0032-3861(91)90459-V