Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e. , the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered b...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (49), p.5999-62
Hauptverfasser:	Kawasaki, Tsuneomi, Kaimori, Yoshiyasu, Shimada, Seiya, Hara, Natsuki, Sato, Susumu, Suzuki, Kenta, Asahi, Toru, Matsumoto, Arimasa, Soai, Kenso
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Autocatalysis Chirality Crystallography Electric fields Ferroelectric crystals Ferroelectricity Organic compounds Triglycine sulfate
Online-Zugang:	Volltext
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