Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e. , the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered b...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (49), p.5999-62
Hauptverfasser: Kawasaki, Tsuneomi, Kaimori, Yoshiyasu, Shimada, Seiya, Hara, Natsuki, Sato, Susumu, Suzuki, Kenta, Asahi, Toru, Matsumoto, Arimasa, Soai, Kenso
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Sprache:eng
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Zusammenfassung:Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e. , the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field. In asymmetric autocatalysis with amplification of ee, molecular chirality of highly enantioenriched organic compounds is controlled by a crystal TGS, whose chirality is switchable by changing the direction of the applied static electric field.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc02162a