Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field
Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e. , the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered b...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (49), p.5999-62 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Kawasaki, Tsuneomi Kaimori, Yoshiyasu Shimada, Seiya Hara, Natsuki Sato, Susumu Suzuki, Kenta Asahi, Toru Matsumoto, Arimasa Soai, Kenso |
| description | Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess,
i.e.
, the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
In asymmetric autocatalysis with amplification of ee, molecular chirality of highly enantioenriched organic compounds is controlled by a crystal TGS, whose chirality is switchable by changing the direction of the applied static electric field. |
| doi_str_mv | 10.1039/d1cc02162a |
| format | Article |
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i.e.
, the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
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i.e.
, the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
In asymmetric autocatalysis with amplification of ee, molecular chirality of highly enantioenriched organic compounds is controlled by a crystal TGS, whose chirality is switchable by changing the direction of the applied static electric field.</description><subject>Asymmetry</subject><subject>Autocatalysis</subject><subject>Chirality</subject><subject>Crystallography</subject><subject>Electric fields</subject><subject>Ferroelectric crystals</subject><subject>Ferroelectricity</subject><subject>Organic compounds</subject><subject>Triglycine sulfate</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkU1r3DAQhk1oIWmaS-4BQS4l4NZjebzScdl8QqCXHHozsjTaVdDaG0km-C_0V1e7G1roHObj5WFm4C2KS6i-Q8XlDwNaVzW0tTopzoC3TYmN-PVp36MsF7zB0-JLjK9VDkBxVvxexnm7pRScZmpKo1ZJ-Tm6yLK0XlMgw_r5MPhZu4FYnLxVidi7SxsWc9Yb1XtieuOC8i7Ne175RMENa5Y2xIwLpJMbBzbag6B2O-_yYvJZ31-2jrz5Wny2yke6-Kjnxcv93cvqsXz--fC0Wj6XmmOVSovGLEC0QmNDlkBVuq9blBIFVRbAyF4hEvZWLBorEFo0shVGi9rWHPl58e24dhfGt4li6rYuavJeDTROsauRAzYgG5nR6__Q13EKQ34uUw0ILqHlmbo5UjqMMQay3S64rQpzB1W3d6W7hdXq4Moyw1dHOET9l_vnGv8DQMiMCw</recordid><startdate>20210617</startdate><enddate>20210617</enddate><creator>Kawasaki, Tsuneomi</creator><creator>Kaimori, Yoshiyasu</creator><creator>Shimada, Seiya</creator><creator>Hara, Natsuki</creator><creator>Sato, Susumu</creator><creator>Suzuki, Kenta</creator><creator>Asahi, Toru</creator><creator>Matsumoto, Arimasa</creator><creator>Soai, Kenso</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6332-2096</orcidid><orcidid>https://orcid.org/0000-0002-8060-444X</orcidid></search><sort><creationdate>20210617</creationdate><title>Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field</title><author>Kawasaki, Tsuneomi ; Kaimori, Yoshiyasu ; Shimada, Seiya ; Hara, Natsuki ; Sato, Susumu ; Suzuki, Kenta ; Asahi, Toru ; Matsumoto, Arimasa ; Soai, Kenso</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c350t-f5dd71868c54efe1a0cb2659958e0f11d9ba55e5bf874f85165d968dc82f2353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Asymmetry</topic><topic>Autocatalysis</topic><topic>Chirality</topic><topic>Crystallography</topic><topic>Electric fields</topic><topic>Ferroelectric crystals</topic><topic>Ferroelectricity</topic><topic>Organic compounds</topic><topic>Triglycine sulfate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kawasaki, Tsuneomi</creatorcontrib><creatorcontrib>Kaimori, Yoshiyasu</creatorcontrib><creatorcontrib>Shimada, Seiya</creatorcontrib><creatorcontrib>Hara, Natsuki</creatorcontrib><creatorcontrib>Sato, Susumu</creatorcontrib><creatorcontrib>Suzuki, Kenta</creatorcontrib><creatorcontrib>Asahi, Toru</creatorcontrib><creatorcontrib>Matsumoto, Arimasa</creatorcontrib><creatorcontrib>Soai, Kenso</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kawasaki, Tsuneomi</au><au>Kaimori, Yoshiyasu</au><au>Shimada, Seiya</au><au>Hara, Natsuki</au><au>Sato, Susumu</au><au>Suzuki, Kenta</au><au>Asahi, Toru</au><au>Matsumoto, Arimasa</au><au>Soai, Kenso</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-06-17</date><risdate>2021</risdate><volume>57</volume><issue>49</issue><spage>5999</spage><epage>62</epage><pages>5999-62</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess,
i.e.
, the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
In asymmetric autocatalysis with amplification of ee, molecular chirality of highly enantioenriched organic compounds is controlled by a crystal TGS, whose chirality is switchable by changing the direction of the applied static electric field.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc02162a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-6332-2096</orcidid><orcidid>https://orcid.org/0000-0002-8060-444X</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2021-06, Vol.57 (49), p.5999-62 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Asymmetry Autocatalysis Chirality Crystallography Electric fields Ferroelectric crystals Ferroelectricity Organic compounds Triglycine sulfate |
| title | Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field |
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