Miscible blends of poly(chloromethyl methacrylate) and poly(2-chloroethyl methacrylate) with poly(ε-caprolactone)

The miscibility behaviour of poly(chloromethyl methacrylate) (PCMMA) and poly(2-chloroethyl methacrylate) (PCEMA) with poly(ε-caprolactone) (PCL) was investigated by differential scanning calorimetry. Each of these blends exhibited a single composition-dependent glass transition temperature indicati...

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Veröffentlicht in:	European polymer journal 1991-01, Vol.27 (9), p.927-930
Hauptverfasser:	Neo, M.K., Goh, S.H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Thermal and thermodynamic properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The miscibility behaviour of poly(chloromethyl methacrylate) (PCMMA) and poly(2-chloroethyl methacrylate) (PCEMA) with poly(ε-caprolactone) (PCL) was investigated by differential scanning calorimetry. Each of these blends exhibited a single composition-dependent glass transition temperature indicative of miscibility. Based on the melting point depression of PCL in the blends, the interaction parameters were found to be −0.82 and −0.76 for PCMMA/PCL and PCEMA/PCL blends respectively.
ISSN:	0014-3057 1873-1945
DOI:	10.1016/0014-3057(91)90035-M