Effect of carbonization temperature on fuel and caffeine adsorption characteristics of white pine and Norway spruce needle derived biochars

•White pine and norway spruce needles derived biochars were produced at 500, 700 & 900 ℃.•Calorific values of the biochars increased with carbonization temperature.•All the biochars were microporous in nature and had specific surface areas of 2–168 m2/g.•Biochars obtained at 900 ℃ attained caffe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Industrial crops and products 2021-04, Vol.162, p.113261, Article 113261
Hauptverfasser: Oginni, Oluwatosin, Singh, Kaushlendra
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•White pine and norway spruce needles derived biochars were produced at 500, 700 & 900 ℃.•Calorific values of the biochars increased with carbonization temperature.•All the biochars were microporous in nature and had specific surface areas of 2–168 m2/g.•Biochars obtained at 900 ℃ attained caffeine adsorption capacities of 9.27–11.85 mg/g. The presence of pharmaceutical compounds in drinking water continues to be problematic in recent times. Adsorption of these compounds is an effective way to mitigate these problems to protect aquatic wildlife. Biochar is a renewable resource that can be used as an adsorption media in this role. This study explored the use of white pine (Pinus strobus) and Norway spruce (Picea abies) needles as feedstocks for producing biochars, which can be utilized as both an adsorbent and solid fuel. The effect of carbonization temperature (500, 700, & 900 ℃) on the solid fuel and caffeine adsorption characteristics of biochars derived from these feedstocks were investigated. The calorific values increased from 29.09–30.30 MJ/kg and 26.62–27.44 MJ/kg for white pine and Norway spruce needle derived biochars, respectively as the carbonization temperature increased. The ignition temperature increased from 390 to 480 ℃ for white pine needle derived biochars and from 368 to 400 °C for Norway spruce needle derived biochars as the carbonization temperature increased. The burnout temperatures for white pine needle derived biochars were between 670–775 ℃ while Norway spruce needle derived biochars presented burnout temperatures of 679–685 ℃. The specific surface areas of the biochars were between 1.72 and 167.71 m2/g. The monolayer caffeine adsorption capacities (qm) of the NS900 and WP900 biochars were 9.27 and 11.85 mg/g, respectively.
ISSN:0926-6690
1872-633X
DOI:10.1016/j.indcrop.2021.113261