Dynamics of the high-intensity multiphoton ionization of N2

The intensity dependence of the multiphoton photoelectron spectrum of N2 has been obtained with subpicosecond laser pulses up to intensities of 10 to the 15th W/sq cm. Both Rydberg and valence states are observed to be ac Stark shifted into intermediate resonance during the photoionization process, although the valence states are seen only at low intensities. It is shown that the vibrational structure of the molecular Rydberg states cancels out in the photoelectron spectrum leading to sharp atomiclike series, even at high intensities. Photoelectrons from the ionization of each of the 3 sigma(g), 1pi(u), and 2 sigma(u) electrons are clearly distinguished. Implications for the interpretation of multiphoton dissociation experiments are discussed. (Author)