A Useful Method for the Conversion of Olefins to Nitro Olefins

Triflyl nitrate is easily generated from tetra-n-butylammonium nitrate in CH2Cl2 solution and serves as an effective nitrating agent for a wide range of unsaturated substrates to form nitro olefins.

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Veröffentlicht in:Organic letters 2021-05, Vol.23 (9), p.3399-3402
Hauptverfasser: Reddy, G. Sudhakar, Corey, E. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Triflyl nitrate is easily generated from tetra-n-butylammonium nitrate in CH2Cl2 solution and serves as an effective nitrating agent for a wide range of unsaturated substrates to form nitro olefins.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.1c00868