Ionization of organic molecules with metal ions formed in the laser plasma

A laser plasma ion source was used to ionize volatile organic compounds in a gas sample. The plasma was generated on a metal target in the intermediate vacuum region of ~0.3 Torr using a pulsed Nd:YAG laser with a wavelength of 1 μm. The resulting ions mass spectra were acquired using orthogonal time‐of‐flight mass spectrometer (O‐TOF MS). When using a copper target, the ions formed are simple complexes (CuM+) of copper ions with organic molecules. The possibility of online identification of trace amounts of alkanes in nitrogen and air, with a detection limit of ~10 ppb, was demonstrated. The ionization efficiency of volatile organic compounds through the formation of clusters with metal ions is 10−4 in terms of the quasimolecular complex ions. The rate constants of ion‐molecular reactions of copper ions with octane and water molecules in nitrogen and air are estimated.