Synthesis of 85 K BiSrCaCuO superconductor
Synthesis of the compound Bi 2Sr 2-yCaCu 2O x, 0≤y≤0.5, was attempted from 10 4 to 10 6 Pa oxygen pressure. Lower pressures and temperatures less than 800°C proved most effective in forming the 85-K superconducting material. A Sr-deficient stoichiometry exhibited highest phase purity. Results sugges...
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Veröffentlicht in: | Materials research bulletin 1990-02, Vol.25 (2), p.251-256 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Synthesis of the compound Bi
2Sr
2-yCaCu
2O
x, 0≤y≤0.5, was attempted from 10
4 to 10
6 Pa oxygen pressure. Lower pressures and temperatures less than 800°C proved most effective in forming the 85-K superconducting material. A Sr-deficient stoichiometry exhibited highest phase purity. Results suggest, however, that presence of a small amount of a phase such as the low-temperature superconductor, Bi
2Sr
2CuO
6, has little effect on the resulting superconducting properties. |
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ISSN: | 0025-5408 1873-4227 |
DOI: | 10.1016/0025-5408(90)90052-4 |