Spectrophotometric determination of the styrene content of alpha-methylstyrene-styrene copolymers

The electronic absorption spectra of polystyrene and poly(alpha-methylstyrene) show a great difference in the extinction coefficient values at 226 nm. On the basis of this fact, it is shown that the styrene content of styrene--alpha-methylstyrene copolymers can be determined by ultraviolet spectroph...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 1988-12, Vol.20 (6), p.543-548
Hauptverfasser: GUENTHER SOARES, B, DE SOUZA GOMES, A
Format: Artikel
Sprache:eng
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Zusammenfassung:The electronic absorption spectra of polystyrene and poly(alpha-methylstyrene) show a great difference in the extinction coefficient values at 226 nm. On the basis of this fact, it is shown that the styrene content of styrene--alpha-methylstyrene copolymers can be determined by ultraviolet spectrophotometry. The relationship between the extinction coefficient at 226 nm and the polystyrene content in the mixture shows a linear dependence. 9 ref.--AA
ISSN:0170-0839
1436-2449
DOI:10.1007/BF00263670