Radiolysis of Polymers of Chlorine Methacrylates

Radiolysis of Polymers of Chlorine Methacrylates

Polymers of alpha -chloroacrylate (MCA), 1-chloroethyl methacrylate (1CEMA), 2-chloroethyl methacrylate (2CEMA), 2,2,2-trichloroethyl methacrylate (trCEMA) and 1,2,2,2-tetrachloroethyl methacrylate (teCEMA) were gamma -irradiated at 77 K. The primary radicals were generated by the abstraction of chl...

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Veröffentlicht in:Journal of polymer science. Polymer chemistry edition 1988-09, Vol.26 (10), p.2669-2681
Hauptverfasser: Wuensche, P, Mueller, S, Lorkowski, J-J
Format: Artikel
Sprache:eng
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Zusammenfassung:Polymers of alpha -chloroacrylate (MCA), 1-chloroethyl methacrylate (1CEMA), 2-chloroethyl methacrylate (2CEMA), 2,2,2-trichloroethyl methacrylate (trCEMA) and 1,2,2,2-tetrachloroethyl methacrylate (teCEMA) were gamma -irradiated at 77 K. The primary radicals were generated by the abstraction of chlorine. They decay or change into chain and radicals upon warming up to room temperature. 17 ref.--AA
ISSN:0360-6376